$C_{2v}$-TOP INTERNAL ROTATION IN THE HIGH-RESOLUTION UV SPECTRA OF WEAKLY BOUND COMPLEXES: II. $APPLICATIONS.^{a}$
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Date
2001
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Ohio State University
Abstract
The model of a $C_{2v}$ top --- $C_{s}$ frame internal rotation discussed in Part I has been used in the analysis of rotationally resolved $S_{1} \leftarrow S_{0}$ fluorescence excitation spectra of three different complexes; aniline$-N_{2}$, para-difluorobenzene$-N_{2}$, and benzonitrile$-H_{2}O$. The results of the internal rotation analysis as well as the structure determination will be presented and the limits of the applied model will be discussed.
Description
$^{a}$Work supported by the Swiss National Science Foundation and NSF.
Author Institution: Department of Chemistry, University of Pittsburgh; Department of Chemistry, University of Pittsburgh
Author Institution: Department of Chemistry, University of Pittsburgh; Department of Chemistry, University of Pittsburgh