SELECTIVE FOURIER TRANSFORM SPECTROSCOPY OF RADICALS

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1988

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Ohio State University

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Two types of selective detection of paramagnetic species, based on Zeeman effect, have been examined with both Fourier transform and diode laser spectrometers. A magnetic modulation requires both a constant and a periodic magnetic fields: however a variation of the magnetic field in a plasma induces, in addition to Zeeman modulation, a non selective modulation concentration. This effect is avoided with a polarization modulation which needs a polarizing system and a constant magnetic field only. We present here experimental results obtained using these technics.

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Author Institution: Laboratoire d'Infrarouge, Associ\'{e} au C.N.R.S., B\^{a}t. 350, Universit\'{e} Paris XI; Laboratoire de Physique Moleculaire et Atmospherique, C.N.R.S. et Universite Pierre et Marie Curie

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