WOOD'S BAND REVISITED

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Date

1978

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Ohio State University

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Abstract

Woods band at 3840 {\AA}, Variously attributed to $Sio^{+1,2,3}$ and $SiN,^{4}$ has been conclusively shown to belong to $SiO^{+}$ from it s isotope shift with $^{18}O$. Rotational constants and spin splitting constants of the upper and lower $^{2}\Sigma$ states have been obtained from the 0-0 and 1-1 bands for both isotopic species. A good estimate of $\omega_{O}{^{\prime}}$ and $\omega_{O}{^{\prime\prime}}$ from these data allows the identification of these states with the $B^{2}\Sigma$ and $X^{2}\Sigma$ states of $SiO^{+}$ recently found by E. A. Colbourn $et al^{5}$ in their photoelectron spectroscopy work.

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$^{1}$L.H. Woods, Phys. Rev. 63, 426 (1943). $^{2}$S. Nagaraj and R.D. Verma, Can. J. Phys. 46, 1597 (1968). $^{3}$M. Singh, H. Bredohl, F. Remy and I. Dubois, J. Phys. B 6, 2656 (1973). $^{4}$T. M. Dunn, K.M. Rao, S. Nagaraj and R. D. Verma, can. J. Phys. 47, 2128 (1969). $^{5}$E. A. Colbourn, J. M. Dyke, E.P.E. Lee, A. Morris and I. R. Trickle, Private communication.""
Author Institution: Department of Physics, University of New Brunswick

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