VIBRATIONAL SPECTRA AND MOLECULAR SYMMETRY OF TETRASILYLHYDRAZINE AND TETRASILYLHYDRAZINE-$D_{12}$

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1976

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Ohio State University

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The Raman spectra of tetrasilylhydrazine, $N_{2}(SiH_{3})_{4}$ , and tetrasilylhydrazine-$d_{12}, N_{2}(SiD_{3})_{4}$ , have been recorded for the gas, liquid and solid phases from 25 to $2500 cm^{-1}$. The infrared spectra of both molecules have been recorded for the gas and solid phases from 90 to $2500 cm^{-1}$. A vibrational assignment based on observed isotopic shift ratios, relative band intensities, depolarization values, and previously reported work on similar molecules will be presented.

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Author Institution: Department of Chemistry, University of South Carolina

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