INFRARED SPECTRA OF MAGNESIUM HALIDES IN SOLID ARGON AND KRYPTON MATRICES

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1964

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Ohio State University

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The infrared absorption spectra of magnesium fluoride and magnesium chloride isolated in solid krypton and argon matrices have been investigated from $240-4000 cm^{-1}$. The molecules were generated in a high temperature cell and trapped at liquid $H_{2}$ and He temperatures. The spectrum of $MgF_{2}$ indicates that the apex angle F---Mg---F is $160^{\circ} \pm 20^{\circ}$. Complete assignment and other details will be discussed.

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Author Institution: Space Science Laboratory, General Electric Company; Cryogenic Laboratory, The Ohio State University

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