MATRIX ISOLATION STUDY OF THE REACSATION OF FATOMS WITH $C_{2}H_{2}$. VIBRATIONAL SPECTRUM OF THE 2-FLUOROVINYL FREE RADICAL
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Date
1980
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Ohio State University
Abstract
Upon condeposition at 14 K of an $Ar:C_{2}H_{2}$ sample with an $Ar:CF_{4}$ sample that had been passed through a low-power microwave discharge, several new absorption appeared which could be assigned to the 2-fluorovinyl free radical. Detailed isotopic substitution studies support this assignment. The results of a least-squares force constant fit to the isotopic data will be presented. The infrared spectroscopic identification of the products of the secondary photodecomposition of the 2-fluorovinyl free radical will also discussed.
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