PROTON NMR STUDY OF ROTATIONAL DYNAMICS OF MATRIX ISOLATED METHYL COMPOUNDS: $CH_{3}Cl, CH_{3}CN$ AND $CH_{3}C_{2}H_{2}$

Semack, M. G.; White, David

PROTON NMR STUDY OF ROTATIONAL DYNAMICS OF MATRIX ISOLATED METHYL COMPOUNDS: $CH_{3}Cl, CH_{3}CN$ AND $CH_{3}C_{2}H_{2}$

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Date

1979

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Semack, M. G.

White, David

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Ohio State University

Abstract

The proton NMR spectra of several symmetric top molecules, $C H 3 C l, C H 3 C N$ and $C H 3 C 2 H 2$ isolated in an argon matrix are reported. The temperature dependence of the lineshapes and the spin lattice relaxation times have been measured in the range 5.5 to 40K. The results are discussed in terms of the tunneling rotation of the $C H 3$ -groups and molecular reorientations in the matrix.

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http://hdl.handle.net/1811/10834

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Abstracts of OSU International Symposium on Molecular Spectroscopy 1970-1979

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PROTON NMR STUDY OF ROTATIONAL DYNAMICS OF MATRIX ISOLATED METHYL COMPOUNDS: $CH_{3}Cl, CH_{3}CN$ AND $CH_{3}C_{2}H_{2}$

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