DIFFERENCE FREQUENCY LASER SPECTROSOCPY OF THE 5g-4f RYDBERG TRANSITIONS OF $H_{2}$

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1994

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Ohio State University

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In our search for the clusive spectrum of CH5+ in a methane-hydrogen discharge, we have found many strong negative-ion-shaped absorption lines in the 2500cm−1 region. The large linewidth and the fact that it appears in pure H2 discharge confirms that it is hydrogenic species. We compared the frequencies with those form two of the more recent studies1,2 of the 5g-4f spectra of H2 and saw that, indeed, they belonged to H2. However, we were able to obtain about twice as many lines than the previous works, owing to the greater sensitivity achievable in our spectrometer. The analysis is currently in progress, being undertake primarily by Dr. J.K.G. Watson.

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  1. Ch. Jungen, I. Dabrowski, G. Herzberg, M. Vervloet. J. Chem. Phys. 2289. 1990. 2. P.B. Davies, M.A. Guest, R.J. Stickland, J. Chem. Phys. 93. 5417. 1990.

Author Institution: Department of Chemistry, The University of Chicago

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