STARK EFFECT AND TORSIONAL MOTION INTERACTION IN BIPHENYL
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Abstract
Although the interaction of an electric field with molecular motions has been thoroughly investigated in the case of a rigid molecule,~{\bf 74} (1995) 4623.} much less results are available for a non-rigid molecule, like the biphenyl molecule, displaying an internal torsional motion strongly coupled to the electric field. The present paper reports an exact calculation of the rotation-torsion energy levels of a biphenyl molecule interacting with an electric field. This molecule, with formula (C
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Friedrich and Herschbach, {\em Phys.\ Rev.\ Lett.Merer and Watson, {\em J.\ Mol.\ Spectrosc.Ramakrishna and Seideman, {\em Phys.\ Rev.\ Lett.
Author Institution: LISA, UMR 7583 CNRS/Universites Paris 12 et 7, 61 Avenue du; General de Gaulle, 94010 Creteil Cedex, France; Unidad de Quimica y Bioquimica, Departamento de; Biotecnologia, ETSI Montes; Universidad Politecnica de Madrid, 28040 Madrid, Spain; Instituto de Estructura de la Materia, CSIC; Serrano 121, 28006 Madrid, Spain