REINVESTIGATION OF THE COMET-TAIL $(A^{2}\Pi_{i}-X^{2}\Sigma^{+})$ SYSTEM OF $^{12}C^{16}O^{-}$

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1997

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Ohio State University

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The emission spectrum of the A2ΠiX2Σ+ system of 12C16O+ produced in the cathode glow of a hollow cathode discharge tube of special design1 and photographed in the spectral region 3345-8500 {\AA} at high resolution2 was reinvestigated. Detailed rotational analysis of ten bands involving five vibrational levels v=0 to 4 of each of the A and X states was carried out. Spin-splitting of the rotational levels was observed for the analyzed bands. The observed intensity distribution of the branches is found to be in good agreement with theoretical calculations. Rotational constants for both the A and X states were obtained from a global fit of the present data of the A-X system and the infrared and microwave data available from the literature. The Fortrat diagram for the 0-2 band confirms that the A2Πi state changes from Hurd’s case (a) at lower J values to Hund’s case (b) at higher J values.

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1S. P. Reddy and C.V.V. Prasad, J. Phys. E. Sci. Instrum. 22, 1972 (1989). 2 C. Haridass, C. V.V. Prasad and S.P. Reddy, Astrophys. J. 338, 669 (1992).


Author Institution: Department of Physics and Physical Oceanography, Memorial University of Newfoundland

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