HIGH RESOLUTION INFRARED SPECTRA OF THE $^{18}O^{16}O^{18}O(C_{2}\nu$) OZONE MOLECULE (1200 TO $500 cm^{-1}$. LINE POSITIONS

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2002

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Ohio State University

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After the previous systematic analysis of 16O31,18O32,16O18O16O3,4 in medium infrared, we present here the results of the analysis of new 18O16O18O observed bands. The spectra have been recorded with the FTS of Reims5,6, with a resolution of 0.006cm−1, and products pathlength × pressure up to 32m×3 Torr. The data reduction to derive line positions uses a new multifit program7. The analysis of spectra is performed using the same formalism as in references [1-4], using standard Watson's Hamiltonian for diagonal blocks and Coriolis and Fermi resonances for off diagonal blocks. 8 polyads have been analysed, among them 7 being analysed for the first time. They correspond to 10 observed bands (underlined) in interaction with ``dark'' bands. (ν1,ν3);(ν2+ν3,ν1+ν2);(ν2+2ν3,ν1+ν2+ν3,2ν1+ν2);(3ν3,ν1+2ν3,2ν1+ν3);(ν2+3ν3);(ν1+3ν3,4ν3);(ν1+ν2+3ν3,ν2+4ν3)and(5ν3) We give here the range of J and Ka for observed transitions, statistics for energy levels, spectroscopic parameters and resonance coupling parameters. Acknowledgments: Authors thank S.A Tashkun for use of GIP programs, X. Thomas and P. Von der Heyden for recording spectra, L. R'{e}galia and J. J. Plateaux for the use of multifit program. 1. S. M. Mikhailenko, A. Barbe, VI. G. Tyuterev and A. Chichery, Atmos. Oceanic Opt., 12, 9 (1999) 2. A. Chichery, A. Barbe, VI. G. Tyuterev, J. Molecular Spectrosc., 206, 1 - 26 (2001) 3. A. Chichery, A. Brabe, VI. G. Tyuterev, S.A. Tashkun, J. Molecular Spectrosc., 205, 347-349 (2001) 4. M. R. De Backer Barilly, A. Barbe, VI. G. Tyuterev, A. Chichery, Mol. Phys., accepted (2002). 5. J.J. Plateaux, A. Barbe, and A. Delahaigue, Spectrochim. Acta, A 51, 1153-1196 (1995). 6. L. R'{e}galia, Thesis Universit'{e} de Reims, (France) (1996). 7. J.J. Plateaux, L. R'{e}galia, C. Boussin and A. Barbe, J.Q.S.R.T., 68, 507-520 (2001).

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Author Institution: Groupe de Spectrom'etrie Mol'eculaire et Atmosph'erique, UMR CNRS 6089 Universit'e de Reims - Moulin de la Housse - BP 1039

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