ELECTRONIC STATES OF DOUBLY IONIZED AMMONIA AND ETHYLENE

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1975

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Ohio State University

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Double ionization potentials corresponding to the formation of the lower-lying electronic states of $NH_{3}^{++}$ and $C_{2}H_{4}^{++}$ have been measured by means of double charge transfer spectroscopy. The measurements are compared with the results of accurate ab initio SCF-CI calculations on $NH_{3}^{++}$ and $C_{2}H_{4}^{++}$ Good agreement between calculated and experimental double ionization potentials is obtained, leading to a full interpretation of the double charge transfer spectra of $NH_{3}$ and $C_{2}H_{4}$

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This work was performed at Laboratoire de Photophysique Moleculaire, Universite de Paris, Sud, 91405, Orsay, France.""
Author Institution: Laboratoire des Collisions Ioniques, Universite de Paris Sud, 91405; Exxon Research and Engineering Company, Corporate Research Laboratory

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http://hdl.handle.net/1811/9462

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Abstracts of OSU International Symposium on Molecular Spectroscopy 1970-1979