OBSERVATION OF FINE STRUCTURE IN THE $Q_{1-1}$ (1) TRANSITION OF ORTHOHYDROGEN IMPURITY IN SOLID PARAHYDROGEN

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1989

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Ohio State University

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Hundreds of very sharp spectral lines with typical linewidth of ∼20 MHZ have been observed around the Q1←0(1) transition (at 4146.5673cm−1) of OH2 impurity in a sample of solid pH2(∼99.8%) at 4.2 K. The spectrum from 4137 to 4154cm−1 was recorded using a 115 mm long cell and a difference frequency laser spectroseter with tone-burst modulation. Transition frequencies are reproducible but the intensity changes as O-H2 concentration varies. The complexity of the spectrum may be ascribed to orientational splittings of pairs of O.H2 molecules by EQQ interactions. The preliminary analysis will be discussed. 1W.N. Hardy and A.J. Berlinsky, Phys. Rev. Lett. 34. 1520 (1975). MITCHIO OKUMURA, Division of Chemistry, California Institute of Technology, Pasadena, California 91125

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Author Institution: Department of Chemistry and Department of Astronomy and Astrophysics, The University of Chicago

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