THE MICROWAVE SPECTRUM AND STRUCTURE OF $HNO_{3}-NH_{3}$

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1997

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Ohio State University

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Abstract

We report the microwave spectrum of HNO3NH3 obtained by pulsed nozzle Fourier transform microwave spectroscopy. The complex is the weakly bound precursor to ammonium nitrate, which is an important aerosol in the earth’s troposphere The a-type spectrum has been recorded up to J=3 and the hyperfine structure fully analyzed. The a-type transitions follow a rigid rotor pattern, but the b-type spectra apparently do not. Preliminary analysis of the rotational constants indicates that the nitric acid forms a near- linear hydrogen bond to the ammonia with an intermolacular N-H separation of about 1.8 A. This rather short distance is distance in the context of incipient proton transfer.

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Author Institution: Department of Chemistry, University of Minnesota

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