OPTICAL PHONONS IN TYSONITE RARE EARTH FLUORIDES.

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1968

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Ohio State University

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Results are presented of a far infrared interferometric research program to assess the potential use as host materials for solid state lasers of those rare earth trifluorides crystallizing in the tysonite structure. Kramers-Kronig analyses of the polarized lattice-vibrational reflection spectra of $LaF_{3}, CeF_{3}, PrF_{3}$ and $NdF_{3}$, taken as a close function of temperature between $5^{\circ}$ and $600^{\circ} K$, have led to an assignment of the crystal symmetry of the tysonite structure and have provided an assessment of the strength of non-linear interactions in these materials.

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This work was supported in part by the Joint Services Electronics Program (Contract DA 28-043-AMC 02536(E)), by a N.A.S.A. grant NGR22-009-(237) and by the U.S. Air Force (ESD Contract AF19(628)-6066). Present address of R.P. Lowndes and C.H. Perry: Dept. of Physics, Northeastern University, Boston, Massachusetts 02115.
Author Institution: Spectroscopy Laboratory and Research Laboratory of Electronics, Massachusetts Institute of Technology

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