MICROWAVE SPECTRUM OF DIAZOACETONITRILE $(N_{2}:CH \cdot CN)$.

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1965

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Ohio State University

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The microwave spectrum of N2:CHCN has been studied between 12 and 28 kMc/sec at a temperature of between -30 and −35C. Preliminary rotational constants for the normal isotopic species in the ground state are A=29,102.6 Mc/sec., B=3024.8 Mc/sec., and C=2735.7 Mc/sec. The value of the inertial defect, Δ=+0.291 amu {\AA}2, indicates that the molecule is planar. Lines in the spectrum due to molecules in the first excited state of a vibration with a frequency of approximately 115cm−1 have been observed.

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Author Institution: Division of Pure Physics, National Research Council

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