THE MOLECULAR STRUCTURE OF ETHYL $CHLORIDE^{*}$

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1961

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Ohio State University

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Transitions of the a-type and b-type spectra of CH3CD2Cl, CH2DCH2Cl, C13H3CH2Cl, and CH3C13H2Cl have been measured in the 8 to 30 kme region of the microwave spectrum. The data combined with previous results1,2 on the spectra of CH3CH2Cl35, CH3CH2Cl37, and CH2DCH2Cl35 have enabled a complete determination of the structure by the substitution method. The following parameters are obtained:[FIGURE] The chlorine quadrupole coupling constants have been reanalyzed and will be discussed.

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Supported by grants from the Research Corporation and from the Petroleum Research Fund. 1R.S. Wagner and B. P. Dailey, J. Chem. Phys. 26, 1588 (1957). 2Barchukov, Murina, and Prokhorov, Opt, i Spekt, 4, 521 (1958).


Author Institution: Kedzie Chemical Laboratory, Michigan State University

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