THE MOLECULAR STRUCTURE OF ETHYL $CHLORIDE^{*}$
Loading...
Date
1961
Authors
Journal Title
Journal ISSN
Volume Title
Publisher
Ohio State University
Abstract
Transitions of the a-type and b-type spectra of $CH_{3}CD_{2}Cl$, $CH_{2}DCH_{2}Cl$, $C^{13}H_{3}CH_{2}Cl$, and $CH_{3}C^{13}H_{2}Cl$ have been measured in the 8 to 30 kme region of the microwave spectrum. The data combined with previous $results^{1,2}$ on the spectra of $CH_{3}CH_{2}Cl^{35}$, $CH_{3}CH_{2}Cl^{37}$, and $CH_{2}DCH_{2}Cl^{35}$ have enabled a complete determination of the structure by the substitution method. The following parameters are obtained:[FIGURE] The chlorine quadrupole coupling constants have been reanalyzed and will be discussed.
Description
$^{*}$Supported by grants from the Research Corporation and from the Petroleum Research Fund. $^{1}$R.S. Wagner and B. P. Dailey, J. Chem. Phys. 26, 1588 (1957). $^{2}$Barchukov, Murina, and Prokhorov, Opt, i Spekt, 4, 521 (1958).
Author Institution: Kedzie Chemical Laboratory, Michigan State University
Author Institution: Kedzie Chemical Laboratory, Michigan State University