WAVE NUMBERS, STRENGTHS, WIDTHS AND SHIFTS WITH PRESSURE OF LINES OF $^{16}O_{2}$ IN SYSTEMS a $a^{1}\Delta_{g} -X{^{3}}\sum^{-}_{g}$ AND $b{^{1}}\sum^{+}_{g} - X{^{3}}\sum^{-}_{g}$
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Date
2002
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Publisher
Ohio State University
Abstract
Analysis of newly measured spectral $data^{a}$ for wave number and intensities of transitions of $^{16}O_{2}$ in absorption in systems $a{^{1}}\Delta_{g} \nu =0- X^{3}\sum^{-}_{g}\nu =0$ and $b{^{1}}\sum{_{g}}^{+} \nu=0, 1, 2 -X^{3}\sum{-{g}}^{-}\nu =0$ with proper statistical treatment yields band parameters for excited states, based on parameters for the ground vibrational state valid up to $J=41$, that are the most precise ($\sigma = 0.021, 0.038, 0.043, 0.50 m^{-1}$ respectively) in published form, and strengths of lines that are internally consistent and in satisfactory agreement with other published values.
Description
$^{a}$S.-L. Cheah, Y.-P. Lee and J. F. Ogilvie, J. Quant. Spectrosc. Radiative Transfer, 64, 467-482 (2000)
Author Institution: Department of Chemistry, National Tsing Hua University; Centre for Experimental and Constructive Mathematics, Department of Mathematics, Simon Fraser University
Author Institution: Department of Chemistry, National Tsing Hua University; Centre for Experimental and Constructive Mathematics, Department of Mathematics, Simon Fraser University