VIBRATIONAL SPECTRA AND ASSIGNMENTS OF FUNDAMENTALS OF 1,1-DIFLUOROCYCLOPROPANE AND ITS d$_{2}$ AND d$_{4}$ ISOTOPOMERS
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Date
2006
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Ohio State University
Abstract
Infrared and Raman spectra of 1,1-difluorocyclopropane (DFCP) and its 2,2-{\it d}$_{2}$ and {\it d}$_{4}$ isotopomers have been recorded. Included are gas-phase Raman spectra obtained with an FT instrument and a simplified sample arrangement. A full vibrational assignment has been proposed for the three isotopomers, and normal coordinate calculations have been done in preparation for determining an equilibrium structure for this ring system. A microwave investigation provides the needed rotational constants for a full set of isotopomers of DFCP.} {\textbf{62}}, 2469 (1975).}
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Author Institution: Department of Chemistry and Biochemistry, Oberlin College, Oberlin, OH 44074; School of Chemistry, University of Edinburgh, EH9 3JJ, U. K.