MODE-SELECTIVITY IN THE AUTOIONIZATION DYNAMICS OF HCO

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1997

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Ohio State University

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Abstract

Rotationally resolved autoionization spectra of the HCO radical in high-Rydberg states ($n = 12 - 50$) built on core vibrational states, (010), (020), (030), and (001) have been obtained from rovibrational selected levels of the $^{3}p \pi^{2}\Pi$ Rydberg state. Autoionization dynamics for bending and stretching modes are analyzed and compared.

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Author Institution: Department of Chemistry, Purdue University

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