RAMAN GAS PHASE SPECTRA OF SOME GROUP IV AND TRANSITION METAL TETRAHALIDES

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1972

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Ohio State University

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The gas phase Raman spectra of $CCl_{4}, SiCl_{4}, GeCl_{4}, SnCl_{4}, TiCl_{4}$ and $VCl_{4}$ have been observed at room temperatures with spectral slit widths of at least $1 cm^{-1}$. Isotopic splittings of $\nu_{1}$ and the vibration-rotation band contoursfor the ${\nu_{2}}, {\nu_{3}}$ and ${\nu_{4}}$ vibrations will be discussed. Comparisons of the spectra observed in condensed phases with those in this study will be made.

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Author Institution: National Bureau of Standards

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