STRUCTURE DETERMINATION OF THE $N_{2}O-O_{2}$ BINARY COMPLEX

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1992

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Ohio State University

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We have recorded high-resolution rovibrational spectra of the N2O-O2 van der Waals complex by exciting the N2Oν3 asymmetric stretch using a tunable infrared diode laser. This has been made possible by the construction of an apparatus with high pumping speed and a 5 pulsed slit nozzle. Preliminary data indicates that the complex has a T-shaped geometry. Numerous progressions have been fit. The latest results on this open shell cluster will be discussed.

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Author Institution: U.S. Army Ballistic Research Laboratory; Department of Chemistry, University of Southern California

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