ROTATIONAL STRUCTURE IN SOME HIGHER ELECTRONIC STATES OF GeF

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1973

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Ohio State University

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From analysis of the rotational structure in several emission transitions involving higher electronic states of $^{74}GeF$, molecular constants have been derived for four additional excited states. These are the $C^{2} \Delta$ and $C^{^{\prime}2} \Pi$ states (previously known from lower dispersion $work^{1}$), and two new Rydberg states, $D^{^{\prime}2} \Pi$ and $H^{2} \Sigma^{+}$, which form a complex near 50 $000 cm^{-1}$.

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$^{1}$ R. F. Barrow, D. Butler, J.W.C. Johns, and J. L. Powell, 1959 Proc. Phys. Soc. 73, 317; A. N. Uzikov and Yu. Ya. Kuzyakov. 1969 Vestn. Mosk. Univ. 11 (Khim) 24, 30.
Author Institution: Department of Chemistry, University of British Columbia

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