HIGH RESOLUTION OVERTONE SPECTRA OF SMALL POLYATOMIC HYDRIDES IN THE VISIBLE

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1982

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Ohio State University

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We have obtained photoacoustic spectra of several small polyatomic hydrides in the region $14,000-18,500 cm^{-1}$. Among those to be discussed are $HN_{3}$, HNCO, and the deuterated methanes. The v=5 and v=6 C-H stretching overtones of $HN_{3}$ give discrete, Doppler-limited spectra, even though these states are fairly close to the dissociation limit.

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