OBSERVATION OF CALCIUM AND STRONTIUM MONOFORMATES AND RELATED RADICALS

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1984

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Ohio State University

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The reaction of Ca (or Sr) with formic acid (or acetic acid) in a Broida oven1 produces free radicals of the type M00C−R(M=Ca,Sr;R=H,CH3). Additional species are produced by the reactions of alkaline earth metals with acetone and acetaldehyde. Comparison with alkaline earth monohalides, monohydroxides and monomethoxides will be made. Preliminary experiments and assignments will be described.

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1 J.B. West, R.S. Bradford, J.D. Eversole and C.R. Jones, Rev. Sci. Instrum., 46, 164(1975).


Author Institution: Department of Chemistry, University of Arizona

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http://hdl.handle.net/1811/16591

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Abstracts of OSU International Symposium on Molecular Spectroscopy 1980-1989