MICROWAVE SPECTRA AND STRUCTURE OF METHYLGERMYL CYANIDE
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Date
1983
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Ohio State University
Abstract
The microwave spectra of $CH_{3}^{70}GeH_{2}CN, CH_{3}^{72}GeH_{2}CN, CH_{3}^{74}GeH_{2}CN, CH_{3}^{70}GeD_{2}CN, CH_{3}^{72}GeD_{2}CN$ and $CH_{3}^{74}GeD_{2}CN$ have been recorded in the K-band region. Only a-type transitions have been observed and R-branch assignments have been made for the ground vibrational state. The $v_{o}$ structural parameters have been obtained using the diagnostic least-squares adjustment to fit the rotational constants. These results will be compared to the corresponding quantities in some similar molecules.
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Author Institution: Department of Chemistry, University of South Carolina