THE MILLIMETER AND SUBMILLIMETER WAVE SPECTRA OF $CH^{+}$ AND $H_{3}O{^{+}}$

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1986

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Ohio State University

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We have used the magnetically enhanced negative glow discharge technique that we have previously described to study the millimeter and submillimeter wave spectra of $CH^{+}$ and $H_{3}O{^{+}}$. The $CH^{+}$ was detected in the discharge products of $CH_{4}$ and $H_{2}$ and the $H_{3}O{^{+}}$ in the discharge products of $H_{2}$ and $O_{2}$. For both of these species, either the precursor gases or intermediaries could be trapped at liquid nitrogen temperatures and the interaction of temperature, gas mixture, and observed spectra will be discussed. Observed frequencies and spectral constants will also be given.

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Address of Plummer, Anderson, Herbst, and De Lucia: Department of Physics, Duke University, Durham, NC 27706
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http://hdl.handle.net/1811/17055

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Abstracts of OSU International Symposium on Molecular Spectroscopy 1980-1989