INFRARED DIODE LASER SPECTROSCOPY OF FORMYL CHLORIDE: THE $v_{6}$ BAND

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1991

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Ohio State University

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Formly chloride is an unstable compound with a half life of approximately 30 minutes. The molecule has been observed in the reaction of ozone with chlorinated hydrocarbons. In this study, formyl chloride was prepared by the method of Takeo and Matsumura,1 in which formic acid was passed over PCl5 at room temperature. Based upon low resolution studies,2 the v6 band at 932.3cm−1 (H-C out-of-plane bend) should be perturbed, presumably by a coriolis interaction with with the v4 fundamental (C-Cl stretch) which is a very intense perpendicular band at 739 cm−1. The v6 band, which is a pure C-type band, is very weak and lends itself to study under the high S/N of the diode laser. The results of the analysis and assignment will be discussed.1H. Takeo and C. Matsumura, J. t Chem. Phys. 64, 4536 (1976) 2I.C. Hisatsune and J. Heicklen, Canad. J. Spectrosc. 18, 77 (1973).

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Author Institution: Dept. of Chemistry and Biochemistry, Southern Illinois University

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