ABSOLUTE LINE INTENSITIES IN $^{12}C_{2}H_{2}$: THE $1.5\mu$ REGION

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2002

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Ohio State University

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In the line of our activities aiming at providing reference spectroscopic information in the near infrared range, we measured absolute line intensities in 5 bands of acetylene observed around 1.5μ: the ν1+ν3 band and 3 hot bands involving excitation of the bending modes ν4 and ν5 of 12C2H2 and the ν1+ν5 band of 13C12CH2. These measurements were performed on spectra recorded at a resolution of 0.009cm−1 (Maximum Optical Path Difference = 100 cm) using a Bruker IFS120HR Fourier transform spectrometer. Five spectra were actually recorded at room temperature, with sample pressure - absorption path length products ranging from 0.67 to 2700 mbarxm. Results will be presented and discussed.

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Author Institution: Laboratoire de Chimie Physique Mol'{e}culaire C. P. 160/09, Universit'{e} Libre de Bruxelles

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