ROTATIONAL SPECTRA AND STRUCTURES OF $HCN-CO_{2}$ AND $DCN-CO_{2}$

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1983

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Ohio State University

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The rotational spectra of $HCN-CO_{2}$ and $DCN-CO_{2}$ were observed using the molecular beam electric resonance technique. The following spectroscopic constants were determined: [FIGURE] The molecule is T-shaped with the nitrogen bonded to the carbon of $CO_{2}$. The N-C van der Waals bond length is 3.01\AA and the average angle between the a-axis and the HCN axis is $18^{\circ}$.

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Author Institution: Department of Chemistry, Harvard University

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