THE MICROWAVE SPECTRA AND STRUCTURES OF SOME ISOCYANATES
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Date
1972
Journal Title
Journal ISSN
Volume Title
Publisher
Ohio State University
Abstract
The microwave spectra of substances having the general formula RNCO have been measured in the frequency region 8 - 200 $GH_{z}$. These include particularly isocynic acid, HNCO, for which spectra have been measured for molecules isotopically substituted artificially at N, C, and O; and chlorine isocyanate, $C{\ell}CNO$, for which the spectra of three isotopic species have been measured. The spectra have yielded values for the rotational constants, inertial defects and nuclear quadrupole coupling constants, and internuclear parameters have been determined. Comparison of the structures with those of related molecules will be made.
Description
Author Institution: Department of Chemistry, The University of British Columbia; Division of Physics, National Research Council of Canada