CHARGE-TRANSFER SPECTRA OF (ArKr)$^{+}$ AND (ArXe)$^{+}$

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1985

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Ohio State University

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The charge-transfer spectra of the heteronuclear rare gas ions have been studied $previously.^{1}$ Furthermore, rotational analyses have been accomplished for (HeNe)$^{+2}$ and (HeAr)$^{+}.^{3}$ Nevertheless, the spectra due to the heavier ions are not well understood. New resolved spectra of the charge-transfer transitions of the rare gas ions (ArKr)$^{+}$ and (ArXe)$^{+}$ are presented. The spectra were obtained from a D.C. discharge in a supersonic jet.

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1) Y. Tanaka, K. Yoshino and D. E. Freeman, J. Chem. Phys. 62, 4484 (1975) 2) I. Dabrowski and G. Herzberg, J. Mol. Spect. 23, 183 (1978) 3) I. Dabrowski, G. Herzberg and K. Yoshino, J. Mol. Spect. 89, 491 (1981)
Author Institution: Herzberg Institute of Astrophysics, National Research Council of Canada; Herzberg Institute of Astrophysics, National Research Council of Canada

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