MICROWAVE SPECTRA, STRUCTURE, AND DIPOLE MOMENT OF CIS-1,2,3-TRIFLUOROCYCLOPROPANE

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1975

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Ohio State University

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Abstract

The microwave spectrum of cis-1,2,3-trifluorocyclopropane a product from the ozonolysis of cis-1,2-difluoroethylene described in the preceding paper, has been investigated in the region B-40 GHz. A fit of the oblate symmetric top spectrum gives a rotational constant of 4064.93 ± 0.04 MHz, A molecular structure was determined using the rotational constants obtained from assignments of the monodeutero species, CHFCHFCDF, and the carbon-13 species, 13CHFCHFCHF, The molecular parameters are r(CH)=1.095±0.002A, r(CC)=1.507±0.002A, r(CF)=1.354±0.003A, and (HCF)=112.2±0.2. A dipole moment of 3.89±0−05 D was determined from the second order Stark shifts of the J = 2-3 transition of the symmetric top species, CHFCHFCHF.

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Author Institution: Department of Chemistry, Harvard University

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