SPECTROSCOPY OF SMALL, FUNDAMENTAL SPECIES IN THE MILLIMETER AND SUBMILLIMETER SPECTRAL REGION

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This paper will give a brief summary of a number of recent spectroscopic projects that have been carried out in the Duke Microwave Laboratory. Species to be discussed will include HCO, LiH/LiD, HNO/DNO, CH3OH,HCOOCH3, HOOH, HNO3, and CHD2F. Theoretical approaches to internal rotation, unpaired electronic spin, and Born-Oppenheimer breakdown will be presented. Experimental techniques will also be discussed. In addition to the intrinsic spectroscopic importance of these species, they are also of importance in a number of astrophysical, atmospheric, and quantum electronic systems.

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Author Institution: Department of Physics, Duke University; Department of Physics, University of South Alabama; Department of Chemistry, California Institute of Technology; Department of Physics, University of Brunswick

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