THE ENTHALPY OF FORMATION OF $C_{3}$

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1993

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Ohio State University

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Abstract

The anharmonic nature of the ν2 bending vibration of C3 has a large influence on the thermal functions of this molecule. The thermal functions based on four different models of this bending vibration are considered along with mass spectrometric data of C3 collected both in our laboratory and in other laboratories. The thermal functions reported by Chase et al. (1986)1 are selected as giving the best second and third law enthalpy of formation. The selected enthalpy of formation for C3 is ΔHf,0=814±14 or ΔHf,298=823±14 kJ/mol. The effects of the different models of the bending vibration on the enthalpy of formation will be presented.

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1. M. W. Chase, Jr., C. A. Davies, J. R. Downey, Jr., D. J. Frurip, R. A. McDonald and A. N. Syverud, JANAF Thermochemical Tables, Third edition, (1986).


Author Institution: Department of Chemistry, Texas A&M University

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