ISOTOPIC SHIFTS IN THE $\mu_{3}$ FUNDAMENTAL OF $NO_{2}$
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Date
1954
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Publisher
Ohio State University
Abstract
Experimental studies on isotopically enriched mixtures with a double-beam infrared spectrometer have allowed the effective isolation of the envelope of the $v_{3}$ fundamental for the respective isotopic molecular species $N^{15}O^{16}_{2}, N^{14}O^{16}O^{18}, N^{14}O^{18}_{2}$ and $N^{15}O^{16}O^{18}$. Analysis of the corresponding shifts results in a significant improvement in evaluation of the molecular constants for $NO_{2}$.
Description
Author Institution: Department of Chemistry, Stanford University; Mallinckrodt Chemical Laboratory, Harvard University