ABSOLUTE CHEMILUMINESCENCE CROSS SECTIONS AND PHOTON YIELDS FOR $M^{*} + N_{2}O$ (M = Mg, Ca, Sr)

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1978

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Ohio State University

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Chemiluminescent reactions of metastable alkaline earth atoms with N2O have been studied under single-collision conditions in a beam-gas configuration. Absolute chemiluminescence cross sections are determined by a method which does not require knowledge of the absolute detection efficiency. Photon yields are also derived for the reactions through the use of measured beam attenuation cross sections. In the reaction Ca(3P)+N2O a Chemiluminescence cross section of 6 {\AA}2 and a 10% photon yield are found.

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This work has been supported in part by the National Science Foundation.


Author Institution: Department of Chemistry, The Johns Hopkins University

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