FLUORESCENCE POLARIZATION MEASUREMENTS CONCERNING THE ROLE OF ROTATION IN INTRAMOLECULAR ENERGY TRANSFER
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Date
1984
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Publisher
Ohio State University
Abstract
Quantum and classical theories indicate that fluorescence polarization from electronically excited molecules is greatly reduced if rotation participates in intramolecular vibrational redistribution. This small polarization results when K is not an approximately good quantum number. We compare the results of model calculations to experiments on p-difluoro-benzene.
Description
Author Institution: Department of Chemistry, Harvard University