NEW ANALYSIS OF THE $\nu_3$ AND $\nu_4$ BANDS OF HNO$_3$ BY HIGH RESOLUTION FOURIER-TRANSFORM INFRARED SPECTRA IN THE 7.6 $\mu$m REGION: LINE POSITIONS AND LINE INTENSITIES
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Date
2007
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Publisher
Ohio State University
Abstract
Nitric acid (HNO$_3$) plays an important role in the Earth's atmosphere as a reservoir molecule of NO$_x$ species. This molecule has a strong infrared signature at 7.6 $\mu$m which is one of the most commonly used for the infrared retrieval of HNO$_3$ in the atmosphere together with the 11 $\mu$m one. It is therefore essential to have the best possible spectral parameters in this spectral region. The goal of this work was to get better line positions and intensities for the $\nu_4$ and $\nu_3$ interacting cold bands located at 1303.071 and 1326.182 cm$^{-1}$ respectively as compared to those obtained few years ago }$^,$}: in fact, only the total band intensity was re-sclaled during the recent update in the HITRAN database }, } HNO$_3$ line list at 7.6 $\mu$m region. For this purpose a large set of new high resolution FTS spectra recorded in Giessen and in Denver were analysed. For the line positions and line intensities calculation, the theoretical model accounts for the vibration-resonances which link the energy levels of the 4$^{1}$ and 3$^{1}$ bright vibrational states together with those of several dark interacting states (9$^{3}$ for example, among others). Very preliminary results will be presented.
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Author Institution: Laboratoire Inter Universitaire des Systemes Atmospheriques,; CNRS, Universite Paris 12, 61 Av du General de Gaulle, 94010 Creteil; Cedex France; Justus-Liebig - Universitat, Physikalisch-Chemisches Institut, Heinrich-Buff-Ring 58, D-35392 Gie\ss en, Germany; Department of Physics, University of Denver, Denver, CO 80208,; USA