FLUORESCENCE STUDIES OF MATRIX ISOLATED TRANSITION METAL ATOMS COMPLEXED WITH SMALL UNSATURATED MOLECULES

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1983

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Ohio State University

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Abstract

Experiments in which Fe or Co atoms are matrix isolated in argon or krypton previously doped with small amounts of ethylene, acetylene and hexafluorobutyne show a number of fluorescence bands in the yellowred region. A study of the laser excitation frequency of these fluorescence features and our interpretation of their origins will be discussed.

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Author Institution: Department of Chemistry and Laboratory for Research on the Structure of Matter, University of Pennsylvania

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