FLUORESCENCE EXCITATION SPECTROSCOPY OF THE $NH_{2} A^{2}A_{1} - X^{2}B_{1}$ SYSTEM IN THE REGION 290-430 NM

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2003

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Ohio State University

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The fluorescence excitation spectrum of the NH2A2A12B1 system has been measured in the region from 290 to 430 nm under jet-cooled conditions using a pulsed discharge source. A total of fourteen bands involving the pure bending states (0,ν2,0) were observed and analyzed, including ten bands not previously measured to our knowledge. The spectra are largely free from rotational perturbations at the low N values accessed in this experiment, and the molecular constants were obtained from a least squares fit to the determined spin-rovibronic term values. The derived constants are in good agreement with theoretical predictions incorporating the effects of orbital angular momentum on the spin-rotational fine structure.

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Author Institution: Department of Physics and Engineering Technologies, Bloomsburg University; Department of Chemistry, Marquette University

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