THE FAR ULTRAVIOLET SPECTRUM OF THIOFORMALDEHYDE
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Date
1978
Journal Title
Journal ISSN
Volume Title
Publisher
Ohio State University
Abstract
The electronic absorption spectrum of thioformaldehyde, $H_{2}CS$ $D_{2}CS$, has been recorded from 2200 to 1800 {\AA}. Four electronic transitions have been identified in the spectrum and have been assigned to the $\pi\rightarrow\pi^{*} n\rightarrow 4s, n\rightarrow 4p_{y}$ and $n\rightarrow 4p_{z}$ electron promotions. Both the $\pi\rightarrow\pi^{*}$ and the $ n\rightarrow 4s$ transitions exhibit discrete vibrational and rotational structure. An analysis of the high resolution spectra of these two lower systems will be discussed.
Description
Author Institution: Department of Chemistry, Brock University; McMaster University, Brock University