THE ROTATIONAL SPECTRUM AND NUCLEAR QUADRUPOLE HYPERFINE STRUCTURE OF $CO_{2}-N_{2}O$
Loading...
Date
1997
Authors
Journal Title
Journal ISSN
Volume Title
Publisher
Ohio State University
Abstract
The rotational spectrum of $CO_{2}-N_{2}O$ has been recorded in the 7-19 GHz region using a pulsed molecular beam, Fourier transform microwave spectrometer of the Balle-Flygare type. Our work was facilitated by the spectroscopic constants obtained in an infrared $study.^{h}$ The hyperfine structure due to the two quadnipolar $^{14} N$ nuclei in the 24 transitions (9 {a} type and 15 b type) have been analyzed using the Watson S-reduce Hamiltonian with the inclusion of hyperfine-interactions to rotational to yield rotational constants, centrifugal distortion constants, and the diagonal components of the nuclear quadropole coupling tensor for each nitrogen nucleus. The rotational constants are consistents with a planar structure with the centers of mass of the subunits separated by 3.472 {\AA}. Because of the planarity of the complex, the angles formed by each subunit to the line connecting the centers of mass (R) cannot be uniquely determined. However if the structure is assumed to be similar to the slipped parallel structures the isoelectronic $CO_{2}$ dimer and $N_{2}O$ dimer then the angle between each subunit and R is about $56^\circ$. $X_{bb}$ for each nitrogen nucleus indicates that the angle between the {b}-axis of The complex and the: $N_{2}O$ molecular axis $(cos^{-1}\sqrt{\langle\cos^{2}\theta^{b}\rangle})$ is approximately $40^\circ$.
Description
$^{h}$C. Dutton, A. Sazonov, and R.A Beaudet, The $51^{st}$ Ohio state University International Symposium on Molecular Spectroscopy, Talk FBO8 (1996).
Author Institution: Department of Chemistry, Mount Holyoke College
Author Institution: Department of Chemistry, Mount Holyoke College