SURFACE COHERENT RAMAN SCATTERING ON ZnO OPTICAL WAVEGUIDES

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1984

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Ohio State University

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The surface coherent Raman scattering (SCRS) effect has been used to obtain Raman spectra of molecules hydrogen-bonded to ZnO surfaces. Two dye laser beams at frequencies ω1 and ω2 are coupled into an oriented, polycrystalline ZnO planar waveguide through SrTiO3 prisms. The evanescent fields are mixed through the X(3) of the surface species to produce a guided wave at ω3=2ω1ω2 which is subsequently coupled out of the waveguide through a second prism. Using interference effects resulting from particular choices of TE modes for the three fields, signals from submonolayer coverages of surface species can be detected.

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Author Institution: Department of Chemistry, University of Arizona; Optical Sciences Center, University of Arizona

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