REFLECTION SPECTRA AND ABSOLUTE INFRARED INTENSITIES IN PURE $LIQUIDS^{*}$

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1960

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Ohio State University

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Infrared reflection spectra of liquid benzene, chloroform, bromoform, carbon disulfide and carbon tetrachloride have been studied. Only one band (the most intense) of each compound gave a measurable reflection peak. The observed reflection bands have been fitted to the dispersion formula developed by $Schatz^{1}$, and absolute intensities have been obtained from the measurements. Comparison is made to absolute intensities obtained from dispersion $studies^{1}$ and to the benzene absorption intensity value determined by Hisatsune and $Jayadevappa.^{2}$

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Author Institution: Department of Chemistry, University of Virginia; Department of Chemistry, University of Southern California
$^{1}$ P. N. Schatz, J. Chem Phys. 29, 958 (1958), 31, 1146 (1959), 32 894 (1960). $^{2}$ I. C. Hisatsune and E. S. Jayadevappa J. chem Phys. 30, 848, (1959), 32, 585 (1960). $^{*}$ This work was supported, in part, by the Office of Ordance Research, United States Army, and, in part, by The National Science Foundation.

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