REFLECTION SPECTRA AND ABSOLUTE INFRARED INTENSITIES IN PURE $LIQUIDS^{*}$

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1960

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Ohio State University

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Infrared reflection spectra of liquid benzene, chloroform, bromoform, carbon disulfide and carbon tetrachloride have been studied. Only one band (the most intense) of each compound gave a measurable reflection peak. The observed reflection bands have been fitted to the dispersion formula developed by Schatz1, and absolute intensities have been obtained from the measurements. Comparison is made to absolute intensities obtained from dispersion studies1 and to the benzene absorption intensity value determined by Hisatsune and Jayadevappa.2

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Author Institution: Department of Chemistry, University of Virginia; Department of Chemistry, University of Southern California


1 P. N. Schatz, J. Chem Phys. 29, 958 (1958), 31, 1146 (1959), 32 894 (1960). 2 I. C. Hisatsune and E. S. Jayadevappa J. chem Phys. 30, 848, (1959), 32, 585 (1960). ∗ This work was supported, in part, by the Office of Ordance Research, United States Army, and, in part, by The National Science Foundation.

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http://hdl.handle.net/1811/7952

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Abstracts of OSU International Symposium on Molecular Spectroscopy 1960-1969