THE ULTRAVIOLET BAND SYSTEMS OF ARSENIC MONOFLUORIDE: ROTATIONAL ANALYSIS OF THE $eO^{-}-X_{2}1$ AND $fO^{+}-X_{2}1$ TRANSITIONS
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Date
1977
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Ohio State University
Abstract
The band system of AsF tentatively designated as $B-X_{2}1$ has been $shown^{1}$ to actually consist of two transitions, designated as $eO^{-}-X_{2}1$ and $fO^{+}-X_{2}1$. The $\Omega$-doubling in the cl state, which is due to the proximity of the $eO^{-}$ and $fO^{+}$ states, is interpreted in terms of a model describing the interactions. The rotational lines in the $cl-X_{1}O^{+}, eO^{-}-X_{2}1$ and $fO^{+}-X_{2}1$ transitions are used for this purpose. Some of the principal molecular parameters thus obtained are: [FIGURE]
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$^{1}$Liu and Jones, Can. J. Phys. 50, 1230 (1972).Present address of R. Vasudev: Department of Chemistry, University of Western Ontario, London, Ontario, Canada.
Author Institution: Department of Chemistry, Dalhousie University
Author Institution: Department of Chemistry, Dalhousie University