THE ULTRAVIOLET BAND SYSTEMS OF ARSENIC MONOFLUORIDE: ROTATIONAL ANALYSIS OF THE $eO^{-}-X_{2}1$ AND $fO^{+}-X_{2}1$ TRANSITIONS

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1977

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Ohio State University

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The band system of AsF tentatively designated as B−X21 has been shown1 to actually consist of two transitions, designated as eO−−X21 and fO+−X21. The Ω-doubling in the cl state, which is due to the proximity of the eO− and fO+ states, is interpreted in terms of a model describing the interactions. The rotational lines in the cl−X1O+,eO−−X21 and fO+−X21 transitions are used for this purpose. Some of the principal molecular parameters thus obtained are: [FIGURE]

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1Liu and Jones, Can. J. Phys. 50, 1230 (1972).Present address of R. Vasudev: Department of Chemistry, University of Western Ontario, London, Ontario, Canada.


Author Institution: Department of Chemistry, Dalhousie University

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http://hdl.handle.net/1811/10030

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Abstracts of OSU International Symposium on Molecular Spectroscopy 1970-1979