SUBMILLIMETER LASER STARK SPECTROSCOPY OF $ND_{3}$

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1987

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Ohio State University

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A Laser Stark spectrum has been observed for fully deuterated Amonia ($^{14}ND_{3}$) with the $195\mu m$ line of the DCN laser up to Stark fields of about 58000 V/cm. The rotation-inversion spectra were taken for both parallel and perpendicular polarizations and three distinct families, one above the laser line and two below the laser line, were observed. Tentative identification of the family above the laser line is $a \leftarrow s, J_{K} = 5_{1} \leftarrow 4_{1}$ and those below the laser frequency are $s \leftarrow a, J_{K} = 5_{4} \leftarrow 4_{4}, 5_{3}, \leftarrow 4_{3}$.

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Author Institution: Department of Physics, University of Idaho

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