RESONANCE RAMAN SPECTRA OF PLATINUM PHTHALOCYANINE IN SOLUTION

Loading...
Thumbnail Image

Date

1977

Journal Title

Journal ISSN

Volume Title

Publisher

Ohio State University

Research Projects

Organizational Units

Journal Issue

Abstract

The resonance Raman spectra of platinum phthalocyanine (PtPc) in glassy and liquid alpha-chloronaphthalene were recorded in the region 200 cm−1 to 1600 cm−1 at 77 and 300∘K . Excitation into the (0-0) and higher vibronic absorption regions shows that in the (0-0) transition most of the symmetric modes are resonance-enhanced while only parts of those modes occur in the higher vibronic transitions. We also conclude that the 587 nm transitions is a (0-1), and not a (0-2) band, as is generally believed. Our depolarization studies show ratios greater than 3/4, but much less than infinite. This suggests that PtPc deviates from a strict D4h symmetry.

Description

Author Institution: Departments of physics and Chemistry, Simon Eraser University Burnaby

Keywords

Citation