THE TORSION-ROTATION SPECTRUM OF $D_{2}O_{2}$

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1996

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Ohio State University

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The torsion-rotation spectrum of D2O2 has been recorded in the region from 25 to 600cm−1 at a resolution (1/MOPD) of 0.003cm−1 using a modified Bomem Fourier transform spectrometer. The aim of the study is to improve the torsional potential of D2O2 and to locate the weak oxygen-oxygen stretching fundamental which should lie amongst the torsional levels. So far, the pairs of torsional levels with n=0,1 and 2 and one of the levels with n=3 have been analysed with J and K value up to 30 and 11 respectively. The current state of the analysis will be described.

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Author Institution: Laboratoire de Physique Mol'{e}culaire et Atmosph'{e}riqe, Universit'{e} Pierre et Marie Curie et CNRS; Steacie Institute for Molecular Sciences, National Research Council of Canada

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