THE TORSION-ROTATION SPECTRUM OF $D_{2}O_{2}$

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1996

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Ohio State University

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The torsion-rotation spectrum of $D_{2}O_{2}$ has been recorded in the region from 25 to $600 cm^{-1}$ at a resolution (1/MOPD) of $0.003 cm^{-1}$ using a modified Bomem Fourier transform spectrometer. The aim of the study is to improve the torsional potential of $D_{2}O_{2}$ and to locate the weak oxygen-oxygen stretching fundamental which should lie amongst the torsional levels. So far, the pairs of torsional levels with $n = 0, 1$ and 2 and one of the levels with $n = 3$ have been analysed with J and K value up to 30 and 11 respectively. The current state of the analysis will be described.

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Author Institution: Laboratoire de Physique Mol\'{e}culaire et Atmosph\'{e}riqe, Universit\'{e} Pierre et Marie Curie et CNRS; Steacie Institute for Molecular Sciences, National Research Council of Canada

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