CALCULATIONS AND FIRST QUANTITATIVE LABORATORY MEASUREMENTS OF O$_{2}$ $A$-BAND ELECTRIC QUADRUPOLE LINE INTENSITIES AND POSITIONS

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Frequency-stabilized cavity ring-down spectroscopy (FS-CRDS) was utilized to make quantitative laboratory-based measurements of electric quadrupole transitions within the 16O2 A-band. We report the first observations of eight extremely weak (line intensities ranging from 3x10−30 to 2x10−29 cm molec.−1) transitions within the  NO,  PO, and  RS branches. New theoretical calculations of line intensities and positions are also presented and compared to these measurements. \begin{wrapfigure}[9]{i}{10.5cm} \vspace{-0cm} \hspace*{-0cm} \epsfig{file=OSU_Quad_Abstract222.eps} \end{wrapfigure} Left: Measured spectrum (symbols) and Voigt fit (line) of electric quadrupole line in the wings of the PQ(11) hot band, magnetic dipole line. Peak signal-to-noise ratio on electric quadrupole line is 16:1. Right: Fit-derived peak areas vs. number density for the NO branch electric quadrupole lines.

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Author Institution: Division of Chemistry and Chemical Engineering, California Institute of Technology, Pasadena, CA 91125, USA; Jet Propulsion Laboratory, California Institute of Technology, 4800 Oak Grove Drive, Pasadena, CA 91109, USA; Process Measurements Division, National Institute of Standards and Technology, 100 Bureau Drive, Gaithersburg, MD 20899, USA

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